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IGCSE §5: Solids, Liquids and Gases · IGCSE

The Kelvin Scale and Absolute Zero

Revision notes on The Kelvin Scale and Absolute Zero for the OCR A-level Physics specification (H556). Free to read, with 4 practice questions in the app.

Temperature is a measure of the average kinetic energy of the particles in a substance. Hotter means the particles are moving faster on average.

Absolute zero — the lowest temperature possible, at which the particles have the minimum possible kinetic energy and effectively stop moving. It is −273 °C.

Nothing can be colder, because there is no less kinetic energy than none.

The Kelvin scale starts at absolute zero, so it has no negative values:

T (K) = θ (°C) + 273

and going the other way, θ (°C) = T (K) − 273.

A kelvin is the same size as a degree Celsius, so a change of 10 °C is a change of 10 K. Only the zero point differs. This is why ΔT can be given in either unit in E = mcΔT, while an absolute temperature in a gas law must always be in kelvin.

Why the gas laws need kelvin. Pressure is proportional to absolute temperature, not to Celsius temperature. Doubling the Celsius temperature from 10 °C to 20 °C does not double the pressure — in kelvin those are 283 K and 293 K, a rise of barely 4%. Using Celsius in a gas law is the most reliable way to get a gas question completely wrong, and it is worth converting as the very first line of working every time.

Useful values:

°C K
Absolute zero −273 0
Water freezes 0 273
Room temperature 20 293
Water boils 100 373

Example: a gas at 27 °C is heated to 327 °C. In kelvin these are 300 K and 600 K, so the absolute temperature has doubled and the pressure at constant volume doubles too. In Celsius it looks like a twelvefold increase, which would give a badly wrong answer.

4 questions on The Kelvin Scale and Absolute Zero

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